|
|
ent-copalyl_diphosphate <=> ent-cassa-12,15-diene + diphosphate
|
4.2.3.28
ent-cassa-12,15-diene synthase
|
–
|
BMK
|
|
BRENDA:
BR48888
KEGG:
R09119
MetaCyc:
RXN-4881
|
|
|
|
ent-cassa-12,15-diene + O2 + reduced_flavodoxin <=> ent-11beta-hydroxycassa-12,15-diene + flavin + H2O
|
1.14.14.112
ent-cassa-12,15-diene 11-hydroxylase
|
–
|
K
|
|
BRENDA:
BR49980
KEGG:
R09866
|
|
|
|
ent-cassa-12,15-diene + 3 reduced_flavodoxin + 3 O2 <=> ent-3beta-hydroxycassa-12,15-dien-2-one + 3 flavin + 4 H2O
|
1.14.14.69
ent-cassadiene hydroxylase
|
–
|
K
|
|
BRENDA:
BR52301
KEGG:
R11981
|
|
|
|
ent-cassa-12,15-diene + reduced_flavodoxin + O2 <=> 2alpha-hydroxy-ent-cassadiene + flavin + H2O
|
1.14.14.69
ent-cassadiene hydroxylase
|
–
|
|
|
BRENDA:
BR52302
KEGG:
R11982
|
|
|
|
ent-cassa-12,15-diene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> ent-11beta-hydroxycassa-12,15-diene + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.112
ent-cassa-12,15-diene 11-hydroxylase
|
–
|
M
|
|
MetaCyc:
RXN-12884
|
|
|
|
ent-cassa-12,15-diene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 3alpha-hydroxy-ent-cassadiene + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
M
|
|
MetaCyc:
RXN-15444
|
|
|
|
ent-cassa-12,15-diene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 2alpha-hydroxy-ent-cassadiene + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-15462
|
|
|
|
ent-cassa-12,15-diene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> ent-3beta-hydroxycassa-12,15-dien-2-one + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.69
ent-cassadiene hydroxylase
|
–
|
|
|
MetaCyc:
RXN-18943
|
|
|
|
ent-cassa-12,15-diene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> ent-3beta-hydroxycassa-12,15-dien-2-one + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.69
ent-cassadiene hydroxylase
|
–
|
|
|
MetaCyc:
RXN-19373
|
|
|
|
ent-cassa-12,15-diene + reduced_flavodoxin + O2 <=> 3alpha-hydroxy-ent-cassadiene + flavin + H2O
|
1.14.14.70
ent-sandaracopimaradiene 3-hydroxylase
|
–
|
|
|
BRENDA:
BS429251
|
|
|
|
ent-cassa-12,15-diene + 3 reduced_flavodoxin + 3 O2 <=> ent-cassadien-19-oic_acid + 3 flavin + 4 H2O
|
1.14.14.86
ent-kaurene monooxygenase
|
–
|
|
|
BRENDA:
BS443509
|
|
|
|
ent-cassa-12,15-diene + O2 <=> 3alpha-hydroxy-ent-cassadiene + H2O
|
1.14.14.70
ent-sandaracopimaradiene 3-hydroxylase
|
–
|
|
|
SABIO-RK:
14864
|
|